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1、摘要(1)金屬Zn濺射靶材表面氧化狀態(tài)的改變是引起濺射工藝不穩(wěn)定的主要原因。樣品鼓轉(zhuǎn)速的變化可以改變真空室內(nèi)的氧氣分布,引起靶材表面狀態(tài)的改變,從而導(dǎo)致放電電壓的變化。(2)AZO薄膜的透過率與薄膜的氧化程度密切相關(guān),而Al的有效摻雜是決定AZO薄膜導(dǎo)電性的重要影響因素:AZO薄膜載流子遷移率的大小取決于薄膜的中性雜質(zhì)濃度的大小。(3)利用磁控濺射獲得的AZO薄膜,在氫氣氣氛中經(jīng)550oC退火處理后,樣品的電阻率達(dá)到6.45×10。4Q·cm,550nm波長的透射率達(dá)到85.7%,達(dá)到了可實(shí)用的技術(shù)指標(biāo)。關(guān)鍵詞:透明導(dǎo)電薄膜、ZnO:AI、AZO
2、、載流子濃度、遷移率、中性雜質(zhì)散射、摻雜效率、退火處理IIAbstractAbstractTransparentconductiveZnO:A!(AZO)filmwasusedinthefieldsofsolarcellsandflatpaneldisplay,becauseofitsexcellentelectricalandopticalproperties.AZOfilm,withtheadvantagesofcheapandabundantrawmaterials,andnon-toxic,isconsideredtobethebestc
3、andidatesforsubstitutingITOfilms.Radicalassistedmagnetronsputteringcoater(RASforshort)isanewtypeofcoater.ARAShastheadvantagesofhighdepositionrate,lowCOStandmassproductionability.Therefore,studiesonthefabricationprocessesofAZOfilmsareveryimportantforindustrialapplications.This
4、dissertationstudiedtheinfluencesoftargets,oxygenpartialpressure,A1content,sputteringpowerandpost-annealingtreatmentonthepropertiesofAZOfilms.ProcessparametersoffabricatingAZOfilmsbyR.ASwerestudied,andtheobtainedAZOfilmswerecharacterized.Thedissertationconsistsoffivechapters:I
5、nChapter1,transparentconductivefilmsandtheresearchhistorywerebrieflyintroduced.MethodsoffabricatingZnO:AIfilmsandtheadvantagesofAZOfilmsdepositedbyRASalsoweregiven.Factorswhichaffectingthestabilityofdischargevoltageduringdepositionprocesseswerealsointroduced.InChapter2,weintr
6、oducedthebasicprincipleandmainparametersoftheRASsputteringcoater,aswellasthedepositionparametersofAZOsamples.Thevariouscharacterizationtechniques,includingXRD、SEM、XRF、UV-Vis—IR、XPS、VanderPauwmethodetc.werealsointroducedInChapter3,effectsofoxygenflowrateonthedischargevoltageof
7、ZntargetandA1target,andtherotationspeedofthesampledrumonthestabilityofdischargevoltagewerestudied.InChapter4,theprocessesoffabricatingAZOfilmsbyZnandAItargetswerestudied.TheeffectsofAIcontent,oxygenpartialpressure(bychangingtheArflowrateoroxygenflowrate)andpost-annealingtreat
8、mentontheelectricalandopticalpropertiesofAZOfilmswereinvestigated.ⅡI