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1、浙江大學(xué)碩士學(xué)位論文用一乙醇胺催化合成甘氨酸及其分離研究姓名：盧祖國申請學(xué)位級別：碩士專業(yè)：化學(xué)工程指導(dǎo)教師：蔡振云2003.2.1辯糕大學(xué)碩士學(xué)位論交摘要本論文在總結(jié)了工攮上幾釋霄氯酸璧產(chǎn)工苗靜基磣一匙，掇痿了靂一己髂胺在焦氧化鈉的堿滾中經(jīng)RaneyCu憾化輾化合成甘氨酸鈉，氍經(jīng)中黼。電滲析麒分離援縫曹氯羧靛薪王芑。本文建貴金蠖羨蛙RaneyCu，銼他測戇最健粒徑為200～-400勇，復(fù)擻淑壤掇制在挎0℃～1辨℃，艇威壓力維持在0．5～1．2MPa。通過多次黝對比實騷，}七較了在不嗣罐往裁鶼穩(wěn)楚下～Z。醇黢戇轉(zhuǎn)像率、越箋酸鑣翰選囂髓、愛瘦髓黎要熟時間以及催化劑本
2、身的熬復(fù)使用次數(shù)。實驗結(jié)聚淡明經(jīng)改性的RaneyCu倦化劑有雯好鶼潘瞧窺委彀靜談穗壽命，既褥離了一乙蘸黢靛轉(zhuǎn)傀擎器囂氮酸鐨瓣這擇毪，又繚短r愛痤霾謄瓣，鏷純裁贅?biāo)腩脡勖@孫浚馘主。一己囂藏熬平穩(wěn)轉(zhuǎn)識率勢95％以。E，甘氨陂鋪的選擇性為99％。愛擻舞夔混合匏耀然酸中翻，褥到髓氨酸弱氯億鈉她潼套物。本文糙出用漱滲蜇亍藤勢離韻方法狳轟混合耪中鼴鬣毪獺，濃縮褥委產(chǎn)瀑營氮黢。努剽氍交了不鞫漉螫瓣壤蔽彀浚、魄滲輯效霉、黢鼗攀竣及縫糕茨影嫡，蜜駿取褥了比較滿意魄結(jié)果，甘氨酸的收攀≥92％，縫廢可遮98％，實驗綣糶為中試和工業(yè)放大提供了可靠酶基礁。關(guān)繾誼茁§妊二五§≤：犍R粕。y
3、eh罐瀛魄滲耩簇棼；磊鼗旺太：警疆圭攀健豫囊ABSTRACTOnthebaseofsmnmarizationofseveralprocessestoindustriallysynthesizeglycin#,the搿lp釋studiesartewglycincpreparationprocess：monocthano
4、am／aciscontactedw／ththeaqueoussolutionofsodiumhydroxideandoxygenatedatthepresenceofRaneyCoppercatalysttoobtainsoditmqsaltofgl
5、yeine,whichisneulralizedwithhydrochloricacidandseparaledwithsodiumchlorideusingeleetrodialysisandmembraneseparationtechnologytoobtainpuregb潛ine．琢thisresearchRa魏eyCoppercatalystisdeveloped鍘搬nob／emetals。Theoptimalreactiontemperatureisbetween150’Caid190’C．爵．7MPa““l(fā)。IMPaforpressureand200～
6、400Inuforcatalystsize．"Hu'oughanumberofeon矬astiveexpcriments，wecomparetireconversionrateofmonoethanolamine,辯妖穰v毋嘏潮i髓msaltofglycine，repeatedtimesofcatalystitselfandreactiontimeundertheactionofdifferentcatalysts．Theexperimentresultdemonstratesthatthedevelopede,aneyCoppercatalystcannoton
7、lyimprovetheactivityofthe鞠凇and臻箍thel雌gcv／t％套罐alsoc奢曝increasetheconversionofmonoethanolmnineandshortenthereactiontime．Theconversionofmonoethanohminecallreach95％onLheaverage,theselectivi每ofsodiumsaltofglycineis99％。Thereac嫩xlmixtureiSneutralizedwithhydroddorieacidtoobtainthemixtureofglyc
8、incandsodiumchloride，InthispapertheeleetrodialysisandmembraneseparationtechnoMgyisir翻oduccd協(xié)辯翔l察osodiumchloridefrommix嫩are泌getpure搭yd矬eafterbeingeondense疽WeresearchtheeffectofvariedfluxonlimilxxtelectricalCUI'端蛙time．separatingrateofsodiumchlorideandenergyCOtLsuming．Satisfiedresults8矬o
9、btain
