TiO2納米粒子的制備與其在織物上的應(yīng)用

TiO2納米粒子的制備與其在織物上的應(yīng)用

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時(shí)間:2019-06-25

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1、AbstractWiththedevelopmentoftechnologyandpeople’Slivingstandards,theclothingfibermaterialsrequirednotonlydurable,comfortableandbeautiful,butanumberofotherfunctionalrequirements.Inspiredbyplantsandanimalsinnature、析tllself-cleaningandsuperhydrophobicphenomenon,researc

2、hershaveaimedtofabricateself-cleaningfabricsbyincorporatingn姐。一materials.Furthmore,Sunradiation,especiallyitsUVsegment,isakindofthemostharmfulexternalfactorsthatdamagehumanhealth.ThusimpartingUV-protectiontoclothingmaterialswouldbecomeanincreaselyimportantrequiremen

3、t.PeoplehavepaidattentiontoTi02foritsexcellentUVshieldingandphotocatalyticfunction.Inthispaper,titaniananoparticalswerepreparedbydifferentmethods、砘tlltetrabutyltitanate(rBOT)asrawmaterials.Thefunctionalfabricswereobtainedbycombiningthecoatingoftitaniumdioxide(n02)wi

4、ththesubsequentdodecafluoroheptyl-propyl-trimethoxysilane(DFTMS)modification.Thefunctionalfabricswhichhadexcellentsuperhydrophobicity,UV—shielding,andphotoeatalyticpropertieswereprepared.Detailsarcasfollows:1.n02solwasobtainedbysol·gelmethod謝tllTBOT,anhydrousethanol

5、,hydrochloricacidandwaterasrawmaterials.Theeffectsofhydrochloricacidconcentration,thevolumeofwaterandvariousratioofTBOTonstabilityofTi02solwereinvestigated.Ti02solWascharacterizedbyX-raydiffractionOCRD).Scanningelectronmicroscopy(SEM)andcontactanglemeasurementwereem

6、ployedtocharacterizetreatedfabrics.Theresultsshowedthattheroughnessoftreatedcottonandpolyesterfabricssurfaceisincreased.Basedtheroughnessofsamplessurface,bothcottonfabricsandpolyesterfabicssamplesshowedsuperhydrophobicpropertymodifiedbyDFTMSandthecontactangleisabove

7、l500.2.AnatasetitaniananoparticalswerepreparedbytheSOl由drothermalmethod、)I,itllTBOT,anhydrousethanol,nitricacidandwaterasrawmaterials.TheeffectsofIIITi02納米粒子的制備及其在織物上的應(yīng)用variousratioofTBOT,waterandnitricacidonmorphologyofTi02nanopaRticleson;thesurfaceofpolymerfabrics

8、wereinvestigated.Ti02nanoparticleswere≥characterizedbyX·raydiffractionfXRD).Scanningelectronmicroscopy(SEM),UV-VISspectrophotometryandcont

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