資源描述：
《低溫等離子改性復(fù)合鈣基吸附劑煙氣脫硫?qū)嶒?yàn)研究.pdf》由會(huì)員上傳分享，免費(fèi)在線閱讀，更多相關(guān)內(nèi)容在行業(yè)資料-天天文庫(kù)。
1、化工進(jìn)展2017年第36卷第3期CHEMICALINDUSTRYANDENGINEERINGPROGRESS·1107·低溫等離子改性復(fù)合鈣基吸附劑煙氣脫硫?qū)嶒?yàn)研究丁衛(wèi)科，段鈺鋒，張君，趙文廣，孫益，劉猛（東南大學(xué)能源熱轉(zhuǎn)換及其過(guò)程測(cè)控教育部重點(diǎn)實(shí)驗(yàn)室，江蘇南京210096）摘要：低溫等離子技術(shù)對(duì)固體吸附劑表面具有明顯的改性作用，為研究低溫等離子改性對(duì)復(fù)合鈣基吸附劑脫硫的影響，并開(kāi)發(fā)高效的脫硫吸附劑，分別制取了不同比例的活性炭/復(fù)合鈣基吸附劑（AC/CaO），并在固定床吸附實(shí)驗(yàn)臺(tái)上進(jìn)行脫硫?qū)嶒?yàn)，探究配比、吸附溫度、O2濃度對(duì)SO2吸附
2、效果的影響。在優(yōu)化的實(shí)驗(yàn)條件下，進(jìn)一步探究低溫等離子改性對(duì)復(fù)合鈣基吸附劑脫硫的影響。結(jié)果表明，在最佳實(shí)驗(yàn)條件下，復(fù)合鈣基吸附劑對(duì)SO2的單位質(zhì)量吸附量達(dá)到24.89mg/g，大于純CaO的脫硫效果；通過(guò)低溫等離子處理后的復(fù)合鈣基吸附劑擁有更高的SO2脫除效率，與未改性復(fù)合鈣基吸附劑相比，單位質(zhì)量吸附量提高了61.7%；在SO2和NO的競(jìng)爭(zhēng)脫除反應(yīng)中，經(jīng)過(guò)低溫等離子改性后，復(fù)合鈣基吸附劑脫除污染物向著有利于脫除SO2的方向發(fā)展。關(guān)鍵詞：低溫等離子；復(fù)合鈣基吸附劑；脫硫中圖分類號(hào)：X511文獻(xiàn)標(biāo)志碼：A文章編號(hào)：1000–6613（201
3、7）03–1107–06DOI：10.16085/j.issn.1000-6613.2017.03.045Experimentalstudyondesulfurizationfromfluegasbycalcium-basedcompositesorbentwithnon-thermalplasmatreatedDINGWeike，DUANYufeng，ZHANGJun，ZHAOWenguang，SUNYi，LIUMeng（KeyLaboratoryofEnergyThermalConversionandControlofMinist
4、ryofEducation，SoutheastUniversity，Nanjing210096，Jiangsu，China）Abstract：Non-thermalplasmatechnologyhassignificantmodificationeffectonsolidadsorbentsurface.Inordertostudytheeffectofcalcium-basedsorbentmodifiedbynon-thermalplasmaondesulfurizationanddevelopahighefficientdes
5、ulfurizationadsorbent,thecalcium-basedsorbentswithdifferentratiosofactivatedcarbon（AC/CaO）wereprepared.TheinfluencesofACtoCaOratio，adsorptiontemperature，O2concentrationonthedesulfurizationofcalciumbasedsorbentwerestudiedinafixedbedadsorptiontestbench.Undertheoptimizedex
6、perimentalconditions，theeffectsofnon-thermalplasmamodificationonthedesulfurizationwerefurtherstudied.Resultsshowedthatthemaximumcapacityofpermasscalcium-basedadsorptionforSO2reached24.89mg/gintheoptimalexperimentalconditions，whichwasgreaterthanthepureCaO.Thecalcium-base
7、dsorbentstreatedwithnon-thermalplasmaperformedhigherSO2removalefficiency.Comparedwiththeunmodifiedcalcium-basedsorbent，SO2adsorptioncapacitypermassincreasedby61.7%throughnon-thermalplasmamodification.TherearecompetitiveremovalreactionbetweenSO2andNOwithcalcium-basedsorb
8、ent，however，itwasfavorableforSO2removalafternon-thermalplasmamodification.Keywords：non-thermalplasmatechnology
