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1、礦物巖石地球化學(xué)通報(bào)·研究成果·BulletinofMineralogy,PetrologyandGeochemistryVo1.31No.4,July2012貴州水銀洞金礦構(gòu)造蝕變體稀土元素地球化學(xué)特征楊成富,劉建中,陳睿,王澤鵬。,閆寶文。,夏勇。,莫榮思1.貴州大學(xué)資源與環(huán)境工程學(xué)院,貴陽(yáng)550003;2.貴州省地質(zhì)礦產(chǎn)勘查開發(fā)局105地質(zhì)大隊(duì),貴陽(yáng)550018;3.中國(guó)科學(xué)院地球化學(xué)研究所,貴陽(yáng)550002摘要:水銀洞金礦構(gòu)造蝕變體(SBT)為產(chǎn)出于茅口租(Pm)和龍?zhí)督M(P。z)之間不整合面上的一套強(qiáng)硅化灰?guī)r、灰?guī)r角礫巖、硅化粘土巖組合。采用ICP—MS測(cè)定鉆孔巖芯中構(gòu)造蝕變體樣
2、品稀土元素組成,對(duì)比研究SBT圍巖、區(qū)域巖漿巖及現(xiàn)代海底熱水系統(tǒng)流體稀土元素組成。結(jié)果顯示,SBT的輕重稀土分餾明顯[LREE/HREE一4.92~17.51,(La/Yb)5.94~38.37],曲線右傾型;輕稀土分異明顯,曲線右傾程度大;重稀土分異不明顯,曲線平坦;負(fù)Eu(0.61~0.94)、Ce(0.52~1.07)異常明顯;SBT及圍巖均具有明顯w型稀土元素四分組效應(yīng),而不同于區(qū)域巖漿巖和現(xiàn)代海底熱水系統(tǒng)流體,表明熱液流體來(lái)源以殼源為主。關(guān)鍵詞:構(gòu)造蝕變體;稀土元素;四分組效應(yīng);水銀洞金礦中圖分類號(hào):P595.73文獻(xiàn)標(biāo)識(shí)碼:A文章編號(hào):1007—2802(2012)04—040
3、4一lOGeochemicalCharacteristicsofREEsinStructureAIterationRocksoftheShuiyingdongGoldDeposit,GuizhouProvinceYANGCheng—fu,LIUJian—zhong,CHENRui,WANGZe—peng。,YANBao—wen。,XIAYong。,MORong—si1.Collegeofresourcesandenvironmentalengineering,GuizhouUniversity,Guiyang550002,China}2.GeologicaIParty105,Guizhou
4、BureauofGeologyandMineralExploration&Development,Guiyang550018,China;3.InstituteofGeochemistry,ChineseAcademyofSciences,Guiyang550002,ChinaAbstract:Thestructuralalterationrocks(namedasSBT),composedbyheavilysilicifiedlimestones,silicifiedlime—stonebrecciasandsilicifiedmudstonesarealteredfromthosero
5、cksoverlyingtheunconformitybetweenPermianMaokouFormationandLongtanFormationsintheShuiyingdonggolddeposit,southwestGuizhouProvince,China.REEsconcentrationsinSBTsamplesfromdrillcoreswereanalyzedbyInductivelyCoupledPlasmaMassSpectrom—etrv(ICP—MS).TheresultshowedthatREEsinSBTsamplesarecharacterizedbye
6、nrichmentofLREEs.LREE/HREE一4.92~17.51,(La/Yb)一5.94~38.37,notableLREEfractionationwithright—inclinedREEsdistribu—tionpatterns。negativeEuanomaly(3Eu0.61~0.94)andCeanomalyCe(ace0.52~1.07).Thesecharacteristicsareverysimilartothoseoftheirhostrocks(tetradeffectofREEfoundinbothSBTandhostrocks),andarequit
7、edistinctfromthoseofigneousrocksneartheShuiyindonggolddepositandmodernseafloorhydrothermalfluids.Asaresult,itissuggestedthathydrothermalfluidsintheShuiyindonggolddepositmaymainlyderivefromthecrust.Keywords:struct