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1、中南大學(xué)碩士學(xué)位論文ABSTRACTThethesisdemonstratesasimplewaytoprocesstheoverseaslateriteviareduction—corrosionmethod,whichcanremovetheironwhenextractingthenickelandcobaltinthelaterite,resultingintheseparationofNiandCofromFeInthistext,theprincipleofthecorrosionmethod,theeffectofthepre—reductiontreatmentf
2、orlateriteoncorrosionprocess,andthecorrosionbehaviorofreductive—IateritearestudiedThethermodynamicanalysisofthetreatmentonreductive—lateriteusingcorrosionmethodwereinvestigated,theresultsshowthat,the11ickelandcobarcanbetransferredintoNi”andCo“whiletheironcanbetransferredintoFeOOHbycontrolling
3、thepotentialandpHofthesolutionThelateritewereprocessedbythechloridesegregationmethodanddirectreductionmethod,respectivelyTheresultsshowthatafterheatingfor90minunder1000℃usingchloridesegregationmethod,themetallizationratioofFe.NiandCointhereductive—lateriteare844%.96%and933%.respectivelyAftert
4、hetreatmentonthereductive—lateritebycorrosionprocess,theleachingefficiencyofFe,NiandCoare88%,92.3%and83l%.respectivelyafterheatingfor60minunder1100'C,mixedwith6%coke.themetallizationratioofFe.NiandCointhereductive—lateriteare758%.893%and873%.respectivelyAfterthetreatmentonthereductive—laterit
5、ebycorrosionprocess,theleachingefficiencyofFe,NiandCoare6.9%,864%and686%,respectivelyThecorrosionbehaviorofreductive-lateritewasstudied,takingthelateriteprocessedbychloridizingsegregationprocessasrawmaterialsTheresultsshowthat:(1)Undertheconditionsofacidtooreratio010,gasflowrate5×103Lmin1m一,l
6、eachingtemperature80'C,leachingtime8h,stirringspeed300rmin~,liquidtosolidratio10,leachingefficiencyofFe,NiandCoare99%.909%and802%.respectively(2)ThekineticsanalysisoftheleachingbehaviorofnickelshowsthattheleachingleactionofnickelwascontrolledbytheinterfacialchemicalreactionAndtheactivationene
7、rgyis3101kJmol~中南大學(xué)碩士學(xué)位論文(3)ThepureoxygencallenhancerustingactionUnderthecaseofinlettingthepureoxygen,theleachingefficiencyofFe,NiandCoarerespectively99%,952%and863%whentherustingactionlastsfor4hAndtheleachingbehaviorofnickelwillstopafterther