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1、中南大學(xué)碩士學(xué)位論文ABSTRACTThethesisdemonstratesasimplewaytoprocesstheoverseaslateriteviareduction—corrosionmethod,whichcanremovetheironwhenextractingthenickelandcobaltinthelaterite,resultingintheseparationofNiandCofromFeInthistext,theprincipleofthecorrosionmethod,th
2、eeffectofthepre—reductiontreatmentforlateriteoncorrosionprocess,andthecorrosionbehaviorofreductive—IateritearestudiedThethermodynamicanalysisofthetreatmentonreductive—lateriteusingcorrosionmethodwereinvestigated,theresultsshowthat,the11ickelandcobarcanbetran
3、sferredintoNi”andCo“whiletheironcanbetransferredintoFeOOHbycontrollingthepotentialandpHofthesolutionThelateritewereprocessedbythechloridesegregationmethodanddirectreductionmethod,respectivelyTheresultsshowthatafterheatingfor90minunder1000℃usingchloridesegreg
4、ationmethod,themetallizationratioofFe.NiandCointhereductive—lateriteare844%.96%and933%.respectivelyAfterthetreatmentonthereductive—lateritebycorrosionprocess,theleachingefficiencyofFe,NiandCoare88%,92.3%and83l%.respectivelyafterheatingfor60minunder1100'C,mix
5、edwith6%coke.themetallizationratioofFe.NiandCointhereductive—lateriteare758%.893%and873%.respectivelyAfterthetreatmentonthereductive—lateritebycorrosionprocess,theleachingefficiencyofFe,NiandCoare6.9%,864%and686%,respectivelyThecorrosionbehaviorofreductive-l
6、ateritewasstudied,takingthelateriteprocessedbychloridizingsegregationprocessasrawmaterialsTheresultsshowthat:(1)Undertheconditionsofacidtooreratio010,gasflowrate5×103Lmin1m一,leachingtemperature80'C,leachingtime8h,stirringspeed300rmin~,liquidtosolidratio10,le
7、achingefficiencyofFe,NiandCoare99%.909%and802%.respectively(2)ThekineticsanalysisoftheleachingbehaviorofnickelshowsthattheleachingleactionofnickelwascontrolledbytheinterfacialchemicalreactionAndtheactivationenergyis3101kJmol~中南大學(xué)碩士學(xué)位論文(3)Thepureoxygencallenh
8、ancerustingactionUnderthecaseofinlettingthepureoxygen,theleachingefficiencyofFe,NiandCoarerespectively99%,952%and863%whentherustingactionlastsfor4hAndtheleachingbehaviorofnickelwillstopafterther