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1、摘要本文主要研究了Fe.Cu復(fù)合粉體在高能球磨過(guò)程中能量的儲(chǔ)存以及變化情況對(duì)金屬結(jié)合劑燒緡陛能的影響。通過(guò)對(duì)Fe—Cu復(fù)合粉體進(jìn)行XRD、DSC、掃描電鏡、面分布和燒結(jié)性能的分析來(lái)了解在球磨過(guò)程中的能量?jī)?chǔ)存方式和變化情況,從而證明了這種儲(chǔ)能對(duì)金屬結(jié)合劑的燒結(jié)溫度和性能的影響。實(shí)驗(yàn)結(jié)果表明,隨著球磨加工的進(jìn)行,粉體的顆粒和晶粒尺寸減小,晶格常數(shù)變大。由于晶粒尺寸的減小和品格常數(shù)的變大,使得表面能和界面能增加并產(chǎn)生了大量的缺陷和位錯(cuò)。DSC和掃描電鏡以及面分布分析的結(jié)果表明上述變化是其儲(chǔ)存能量的主要來(lái)源。這些儲(chǔ)存的
2、能量在燒結(jié)過(guò)程中使燒結(jié)溫度大幅度下降。在Fe—Cu二元系中加入金屬sn及663青銅和SiC球磨后,試樣的燒結(jié)性能隨球磨時(shí)間的延長(zhǎng)而提高,其抗折強(qiáng)度在球磨過(guò)程中有一個(gè)最小值;將球磨一定時(shí)間的663青銅和SiC添加劑加入到球磨后的Fe45Cu45Snl0中,其加入量應(yīng)當(dāng)適宜,此時(shí)燒結(jié)體的各項(xiàng)性能(如抗折強(qiáng)度、燒結(jié)密度、硬度)都達(dá)到最高值。這對(duì)金屬基余剛石丁具的生產(chǎn)有著實(shí)際的指導(dǎo)意義。實(shí)驗(yàn)證明,粉末經(jīng)球磨后可以在達(dá)到金剛石工具所要求的性能的條件下大大降低燒結(jié)溫度,從而減少會(huì)剛石的損壞,進(jìn)而提高金剛石工具的質(zhì)量和加工效
3、率,延長(zhǎng)金剛石工具的使用壽命和效率。關(guān)鍵詞機(jī)械合金化復(fù)合粉體Fe—Cu金屬結(jié)合劑儲(chǔ)能高能球磨燒結(jié)體金剛石工具苧當(dāng)盔!!!:蘭竺圭篁蘭AbstractTheenergieshowtobestoredandchangedofFe-Cucompotmdpowdersduringhigh—energyball·rmillingeffectonsintercapabilitiesofmetalbondweremailflydiscussedinthisarticle.Inordertofindoutwaysofstore
4、dandchangeofenergyduringmilling,XRD,DSC,SEM,EDSandsintercapabilitieswereusedtOanalyzethemilledFe—Cucompoundpowders,whichaffectedthesintertemperatureofmetalbondandcapabilityofproducts.Theresultsofexperimentshowedthatcrystallineandgrainsizesofthecompoundpowder
5、swerediminishedgraduallyandcrystallinelatticeparameterswereincreasedgraduallywithmilling.Agreatdealofimperfectionsanddefectswereproducedanddiminishingcrystallinesizesandincreasingcrystallinelatticeparameterincreasedsurfaceenergiesandinterfaceenergies,Theresu
6、ltsofDSC、SEMandEDSshowedthatthemainresourcesofstoredenergieswerefromthischanges.ThesintertemperatureWaSgreatlydecreasedcourseofsinterbythesestoredenergies+ThemetalSn,663bronzeandSiCaftermillingwereaddedtoFe—Cusystem.Thesintercapabilitiesofsamplewerepromotedw
7、ithcontinuemillingtime.The663bronzeandSiCadditivewereaddedtoFe45Cu45Snl0thatwasmilled,theadditiveshouldhemilledsometimeanditsquantityshouldbeappropriated.Inthistime.thekindsofthecapabilitieswereallreachedmaximal.itwasinstructionalsignificancetoproducemetalin
8、tegrateagentdiamondtools.Theexperimentshowedthatthesintertemperatureandthedamnificationofdiamondweregreatlycomedownanddiminishedinconditionofsatisfyingcapabilitiesofdiamondtoolsbymilling.Thequal