名山河流域水稻土微團(tuán)聚體對hg22b吸附—解吸特性-研究

名山河流域水稻土微團(tuán)聚體對hg22b吸附—解吸特性-研究

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時(shí)間:2019-03-03

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1、萬方數(shù)據(jù)AbstractThestudywasengagedinallinvestigationandanalysisoftheeffectsofpaddyfieldsoilcomponentsontheadsorptionanddesorptionofmercurybymicro—aggregatesalongtheMingshanRiverwatershed。Theoreticallyspeaking,wehadalreadymadeclearthatheavymetalcontaminants,suchaSH92+,canstronglyaffectthemigrationofsuchh

2、eavymetalpollutantsintheenvironmentinthegroundwater,theorganismsandcropsinthewatershed.Therefore,inproceedingwithourstudy,wehadcollecteddifferent-sizedmicro—aggregatessamplesandseparatedthembywetsieving--siphonsedimentation—-freezedryingmethodfromthepaddyfieldsinthesaidwatershed.Furthermore,wehaduse

3、dtheisothermaladsorptionmethod,batchmethodandNaN03andHCldesorptionmethodfortracingtheactualkineticandthermodynamicsofmercuryadsorptionanddesorptionviathemicro—aggregates.And,next,wehadderivedthemicro—aggregatessampleswithoutorganicmatters(OM)andfreeironoxides(Fed)respectivelywiththehelpofselectivedi

4、ssolutioninhopingtodisclosetheeffectsofOMandFedinthepaddysoilcomponentsonthemercuryadsorptionanddesorptionTheresultswereaSfollows:ng:+adsorbanceofthebulksoilandmicro—aggregatestendedtoincreasewiththeincreaseofequilibriumconcentration,whichWasinsignificantlypositivecorrelationwiththecationexchangecap

5、acity(CEC),OMandFed僻L0.9746_0.9836).Moreover,theH92+adsorptionisothermsturnedoutwellinaccordwiththeLangmuirequations,nevertheless,thedistributioncoefficient(‰)turnedoutinnegativecorrelation慚ththeinitialconcentrationofH92+.Ontheotherhand,thougIlafterremovingOMandFedfromthesoil,theH92+adsorbanceintheb

6、ulksoilandmicro-aggregatestendedtogetdecreased,thereexistedasignificantlypositivecorrelationwimtheresidualOMandFed.SuchafactindicatesthatthecontributionsofOMandFedremovaltothedecreaSeofadsorbanceturnouttovaryamongthedifferentmicro—aggregatesoftheparticlesizes,、)l,imequivalentcontribution(30%)in0.053

7、4).25mmmicro—aggregatessamplesand10一foldmoreofFedthanOMin<0.002mmmicro—aggregatessamples.Therefore,thedesorptionstudyindicatedthatthedesorptionrateturnedtoincreasewiththeadsorbaneeofHg“.Insuchasituati

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