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《名山河流域水稻土微團(tuán)聚體對hg22b吸附—解吸特性-研究》由會員上傳分享,免費(fèi)在線閱讀,更多相關(guān)內(nèi)容在教育資源-天天文庫。
1、萬方數(shù)據(jù)AbstractThestudywasengagedinallinvestigationandanalysisoftheeffectsofpaddyfieldsoilcomponentsontheadsorptionanddesorptionofmercurybymicro—aggregatesalongtheMingshanRiverwatershed。Theoreticallyspeaking,wehadalreadymadeclearthatheavymetalcontaminants,suchaSH92+,canstronglyaffectthemigrationofsuchh
2、eavymetalpollutantsintheenvironmentinthegroundwater,theorganismsandcropsinthewatershed.Therefore,inproceedingwithourstudy,wehadcollecteddifferent-sizedmicro—aggregatessamplesandseparatedthembywetsieving--siphonsedimentation—-freezedryingmethodfromthepaddyfieldsinthesaidwatershed.Furthermore,wehaduse
3、dtheisothermaladsorptionmethod,batchmethodandNaN03andHCldesorptionmethodfortracingtheactualkineticandthermodynamicsofmercuryadsorptionanddesorptionviathemicro—aggregates.And,next,wehadderivedthemicro—aggregatessampleswithoutorganicmatters(OM)andfreeironoxides(Fed)respectivelywiththehelpofselectivedi
4、ssolutioninhopingtodisclosetheeffectsofOMandFedinthepaddysoilcomponentsonthemercuryadsorptionanddesorptionTheresultswereaSfollows:ng:+adsorbanceofthebulksoilandmicro—aggregatestendedtoincreasewiththeincreaseofequilibriumconcentration,whichWasinsignificantlypositivecorrelationwiththecationexchangecap
5、acity(CEC),OMandFed僻L0.9746_0.9836).Moreover,theH92+adsorptionisothermsturnedoutwellinaccordwiththeLangmuirequations,nevertheless,thedistributioncoefficient(‰)turnedoutinnegativecorrelation慚ththeinitialconcentrationofH92+.Ontheotherhand,thougIlafterremovingOMandFedfromthesoil,theH92+adsorbanceintheb
6、ulksoilandmicro-aggregatestendedtogetdecreased,thereexistedasignificantlypositivecorrelationwimtheresidualOMandFed.SuchafactindicatesthatthecontributionsofOMandFedremovaltothedecreaSeofadsorbanceturnouttovaryamongthedifferentmicro—aggregatesoftheparticlesizes,、)l,imequivalentcontribution(30%)in0.053
7、4).25mmmicro—aggregatessamplesand10一foldmoreofFedthanOMin<0.002mmmicro—aggregatessamples.Therefore,thedesorptionstudyindicatedthatthedesorptionrateturnedtoincreasewiththeadsorbaneeofHg“.Insuchasituati