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1、Chapter5TechniquesinGreenChemistryChapter5∑5.1TheperformanceofCatalystsinChemicalreaction∑5.2GreenChemistryandCatalysisTechniquesin∑5.3TheDesignofHighEfficientandSafeCatalyst∑5.4ChangingStartingMaterialforChemicalreactionGreenChemistry∑5.5ChangingReagents∑5.6
2、ChangingthesolventofChemicalReaction∑5.7ProcessControlandProcessIntensification∑References12SamplesfortheApplicationofCatalystsNreactaprodp/phasTheroleofcatalystT/KontsuctsMPaecatalyst5.15.1TheperformanceofCatalystsinTheperformanceofCatalystsin1/2NFe-Accelera
3、teChemicalreaction2Gas-1+NHKO/Al72340.53reaction322solid3/2HOrate23ControltheCH224CHCPdCl-V0.101liquiSelectivity+32540aHOcomplex3dfor1/2O2differentproducts34CH224C0.101gas-Gas+2Ag/AlO5205CHCCH623~bHO233soli324Al2O3,soliControl4aHOH+HO6831/2O222ddthe2COSelecti
4、vit2CH20.101Gas-24+Ni520yforc+3O23solid(CHGas2H2O5CHC2different35)2OAlO523,soliproductsbHOH233420~2+H2OdnC3H6[C3H6]nO202.6gasa2450CrO·SiO232Gas-3nCH[C3H6]n·Al2O3420~3.1solid-6CH+CO673~0.1013Gasb36or450liquid4Ni/AlO~105,soliaO+H231273MO3·Al2O322h-1)dControlZie
5、gler-the30.101Gas-nC3H6[C3H6]nNatta373solid-Selectivitc3liquidyfor0.1013左旋二6CH+CO2氣體時(shí)Gasdifferent2-(6-甲羥基苯4+Ni/AlO>673空速率,soliproducts氧基-2Gas-bO23丙氨酸2HO~1000d4萘基)丙Rusolid-2h-1(L-烯酸+liquidnaprox氫en)561∑CatalysthasbeencalledasmolecularmachineSynthesizethespecia
6、lAcceleratethechemicalreaction∑Catalysthasbeencalledasmolecularmachineconformationofchiralisomers:rateTheconsiderationofAccelerateselectivelyoneoftheincorporatingthecatalystwiththeseveralthermodynamicallypossiblereactionconditionscouldcontrolreactionsandyield
7、selectivelythetheselectivityofchemicalreaction.specialproducts.∑Highselectivityandatomeconomyisofthemostimportanceinbio-process,andalltheNamely,theuseofcatalystscanreactionsinorganismarecatalyzedbyenzymecontroltheselectivityforspecialwhicharecharacterizedwith
8、highspecificities,products.selectivityandatomeconomy.Controltheenantioselectivityof78Catalysthasbeencalledasmolecularmachine∑RecentinvestigationshavereportedCatalysthasbeencalledasmolecul