鋰電池高溫存放后的電化學容量衰減

鋰電池高溫存放后的電化學容量衰減

ID:39679317

大小:116.91 KB

頁數(shù):6頁

時間:2019-07-09

鋰電池高溫存放后的電化學容量衰減_第1頁
鋰電池高溫存放后的電化學容量衰減_第2頁
鋰電池高溫存放后的電化學容量衰減_第3頁
鋰電池高溫存放后的電化學容量衰減_第4頁
鋰電池高溫存放后的電化學容量衰減_第5頁
資源描述:

《鋰電池高溫存放后的電化學容量衰減》由會員上傳分享,免費在線閱讀,更多相關內(nèi)容在行業(yè)資料-天天文庫

1、JournalofTheElectrochemicalSociety,152~6!A1041-A1046~2005!A10410013-4651/2005/152~6!/A1041/6/$7.00?TheElectrochemicalSociety,Inc.ElectrochemicalInvestigationsonCapacityFadingofAdvancedLithium-IonBatteriesafterStoringatElevatedTemperature,zMao-SungWu,*Pin-ChiJuliaChiang,andJung-ChengLinIndust

2、rialTechnologyResearchInstitute,MaterialsResearchLaboratories,Hsinchu310,TaiwanCapacityfadingofadvancedlithium-ionbatteriesafterelevatedtemperaturestoragewasinvestigatedbythree-electrodemeasure-ments.Capacityfadingofabatteryincreasesbyincreasingthestate-of-charge~SOC!duringstorage,especially

3、atelevatedtemperatures.ThereversiblecapacityofabatterysSOC=100%dat60°Cdecreasesfrom820to650mAh~79.3%capacityretention!after60days.Atroomtemperature,abatterySOCinˉuencesthecapacityfadingonlyslightly;after65daysofstorage,thereversiblecapacitydecreasesfrom820to805mAh~98.2%capacityretention!.Ind

4、ividualeffectsbytheanode,cathode,andelectrolyteoncapacityfadingareanalyzedwiththree-electrodeelectrochemicalacimpedance.Themajorcontribution,fromX-rayphotoelectronspectroscopy~XPS!andenergy-dispersivespectroscopyresults,comesfromcathodedegradationasaresultofcobaltdissolutionattheLiCoO2surfac

5、elayer.Aminorcontributioncomesfromthecontinuousreactionsbetweenlithiatedmesocarbonmicrobead~MCMB!electrodeandelectrolytecomponents,whichinturnthickentheSEI?lmandconsumeavailablelithiumions.FromX-raydiffractionandXPSresults,high-temperaturestorageinˉuencesonlythesurfacepropertiesofMCMBandLiCo

6、O2electrodes;bulkpropertiesremainunchanged.?2005TheElectrochemicalSociety.@DOI:10.1149/1.1896325#Allrightsreserved.ManuscriptsubmittedAugust17,2004;revisedmanuscriptreceivedDecember15,2004.AvailableelectronicallyApril21,2005.Inrecentyears,anewtypeoflithium-ionbattery,theadvancedreferenceelec

7、trodemaybeadded,thenmoremechanismsmaybelithium-ionbattery~ALB,withlaminatedaluminumfoilexterior!,studiedandphenomenaunderstood.Therefore,thispaperistoin-hasemergedbecauseofitshighenergydensity,longcyclelife,andvestigatethecapacityfadingofcommercial

當前文檔最多預覽五頁,下載文檔查看全文

此文檔下載收益歸作者所有

當前文檔最多預覽五頁,下載文檔查看全文
溫馨提示:
1. 部分包含數(shù)學公式或PPT動畫的文件,查看預覽時可能會顯示錯亂或異常,文件下載后無此問題,請放心下載。
2. 本文檔由用戶上傳,版權歸屬用戶,天天文庫負責整理代發(fā)布。如果您對本文檔版權有爭議請及時聯(lián)系客服。
3. 下載前請仔細閱讀文檔內(nèi)容,確認文檔內(nèi)容符合您的需求后進行下載,若出現(xiàn)內(nèi)容與標題不符可向本站投訴處理。
4. 下載文檔時可能由于網(wǎng)絡波動等原因無法下載或下載錯誤,付費完成后未能成功下載的用戶請聯(lián)系客服處理。