資源描述：
《statistical mechanics》由會員上傳分享，免費(fèi)在線閱讀，更多相關(guān)內(nèi)容在學(xué)術(shù)論文-天天文庫。
1、Statisticalmechanics:AselectivereviewoftwocentralissuesJoelL.Lebowitz*DepartmentsofMathematicsandPhysics,Rutgers,TheStateUniversityofNewJersey,Piscataway,NewJersey08854-8019Igiveahighlyselectiveoverviewofthewaystatisticalmechanicsexplainsthemicroscopicoriginsofthetime-asymmetricevolution
2、ofmacroscopicsystemstowardsequilibriumandof?rst-orderphasetransitionsinequilibrium.Thesephenomenaareemergentcollectivepropertiesnotdiscernibleinthebehaviorofindividualatoms.Theyaregivenpreciseandelegantmathematicalformulationswhentheratiobetweenmacroscopicandmicroscopicscalesbecomesveryl
3、arge.[S0034-6861(99)03402-9]I.INTRODUCTIONditiveeffectsoftheactionsofindividualatoms,e.g.,thepressureexertedbyagasonthewallsofitscontainer,Naturehasahierarchicalstructure,withtime,length,whileothersareparadigmsofemergentbehavior,hav-andenergyscalesrangingfromthesubmicroscopictoingnodirec
4、tcounterpartinthepropertiesordynamicsthesupergalactic.Surprisingly,itispossible,andinofindividualatoms.Particularlyfascinatingandimpor-manycasesessential,todiscusstheselevelstantexamplesofsuchemergentphenomenaaretheir-independentlyDquarksareirrelevantforunderstandingreversibleapproachtoe
5、quilibriumandphasetransitionsproteinfoldingandatomsareadistractionwhenstudy-inequilibrium.Bothofthesewould(orshould)beas-ingoceancurrents.Nevertheless,itisacentrallessonoftonishingiftheywerenotsofamiliar.Theirmicroscopicscience,verysuccessfulinthepastthree-hundredyears,derivationandanaly
6、sisformsthecoreofstatisticalme-thattherearenonewfundamentallaws,onlynewphe-chanics.Iwilldiscussthe?rstoftheseinSec.IIandthenomena,asonegoesupthehierarchy.ThusarrowsofsecondinSec.III.explanationsbetweendifferentlevelsalwayspointfromForamoregeneralsurveyofstatisticalmechanicsinsmallertolar
7、gerscales,althoughtheoriginofhigher-thepasthundredyears,thereaderisreferredtothelevelphenomenainthemorefundamentallower-levelotherarticlesinthissectionaswellastomyarticleinlawsisoftenveryfarfromtransparent.(Inadditionthespecialvolumecelebratingthe?rst-hundredyearsofsomeof
