Introduction to Statistical Mechanics I

Introduction to Statistical Mechanics I

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時間:2019-07-31

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1、IntroductiontoIntroductiontoStatisticalMechanicsStatisticalMechanicsMinHuangChemicalEngineeringTongjiUniversityClassicalMechanicsClassicalMechanicsReviewReviewIntroduction?WhatisStatisticalMechanics??Abranchofphysicsthatappliesprobabilitytheorytothestudyofthethermody

2、namicbehaviorofsystemscomposedofalargenumberofparticles.?Statisticalmechanicsprovidesaframeworkforrelatingthemicroscopicpropertiesofindividualatomsandmoleculestothemacroscopicbulkpropertiesofmaterials?Explainingthermodynamicsasaresultofclassicalandquantum-mechanicald

3、escriptionofstatisticsandmechanicsatthemicroscopiclevelFermat’sPrincipleinGeometricOptics?Inhomogeneousmediums,thelightraysgostraight.Attheinterfacebetweendifferentmediums,lightraysgetreflectedorrefracted.?1658theFrenchmathematicianPierredeFermatdemonstratedthatallth

4、reeofthelawsofgeometricopticscanbeaccountedforontheassumptionthatlightalwaystravelsbetweentwopointsonthepathwhichtakestheleasttime(or,morerigorously,theextremaltime)Fermat’sPrincipleinGeometricOptics?Fermatalsoassumed?lighttravelsmoreslowlyindensemediathanitdoesinair

5、?Theopticallength,isdefinedbytheactuallengthofthepathtimestheindexofrefractionofthemedium?Allowingtheindexofrefractiontovaryasafunctionofthepositionn(x),theopticallengthisgivenbyl=∫n(x)dl222wheredl=(dx)+(dy)+(dz)isthelinesegmentalongthepathFermat’sPrincipleinGeometri

6、cOptics?Fermat’sprincipleis?Inotherwords,timestatedmathematicallyastakenforlighttotravelalongitstrueoractualδl=0pathfrompointA?Bisalongtheactualpathofequal“infirstorderalightrayapproximation”tothetimetakenalongother(hypothetical)pathscloselyadjacenttothetruepath.Ferm

7、at’sPrincipleinGeometricOptics?1)Inahomogeneousmedium,theindexofrefractionisaconstant,andtheproblemisjusttominimizethepathlength,correctlychoosingthestraightlines.2)Iftherearetwomediumsattachedatz=0Choosingtheinitialpointas(xi,0,zi)(zi<0,theindexofrefractionn1)andthe

8、finalpoint(xf,0,zf)(zf?Possible>0,theindexofrefraction(hypothetical)pathsn2),theonlyparametertoconnectingpointsAbedeterminedistheva

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