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1、GI產(chǎn)品鋅渣缺陷成因與改善*TheCausesandImprovementsofDrossPick-UpofGIProducts*■林振華JengHuaLin1連續(xù)熱浸鍍鋅線鋅液槽內(nèi)之主要成份為鋅(99.5%以上)、鋁(0.1-0.3%)及鐵(0.03-0.005%),生產(chǎn)時(shí)之溫度控制在460-470℃。如果使用單一鋅槽生產(chǎn)二種產(chǎn)品(GA與GI),在製程轉(zhuǎn)換及成份的調(diào)整過(guò)程中,由於自由鋁與自由鐵的結(jié)合及底渣(Bottomdross,FeZn7,)還原的過(guò)程中,產(chǎn)生大量的浮渣(Floatingdross,Fe2Al5,)。因比重較鋅液小,最後會(huì)浮在鋅液上層,但是在上浮過(guò)程中,受到鋅
2、槽內(nèi)輥?zhàn)拥臄_動(dòng)影響,流至鋼帶而附著在表面造成產(chǎn)品缺陷,這個(gè)產(chǎn)品缺陷稱之為鋅渣附著,無(wú)法符合外露產(chǎn)品的品質(zhì)要求。浮渣的形成有二個(gè)階段,第一階段浮渣的反應(yīng)與鋅槽溫度、自由鋁、自由鐵濃度相關(guān),反應(yīng)時(shí)間大約需2小時(shí)。第二階段底渣還原的反應(yīng)時(shí)間則與底渣數(shù)量有關(guān),一般需2-3天。避免浮渣造成品質(zhì)問(wèn)題之有效對(duì)策,包括:鋅液樣本有無(wú)Fe2Al5之檢驗(yàn),N2攪拌加速底渣還原,析出鐵、析出鋁與溫度之隨時(shí)掌控,加鋅作業(yè)時(shí)Fe、Al與Fe2Al5分佈研究應(yīng)用。Themainchemicalcontentsinthezincbathofthecontinuoushotdipgalvanizinglines
3、areZn(99.5%),Al(0.1-0.3%),andFe(0.03-0.005%).Theoperatingtemperatureofthezincbathissetbetween460-470℃.Whenasinglezincbathisusedtomanufacturetwoproducts(GAandGI),alargeamountoffloatingdrossisformedfromtheunificationoffreeAlandfreeFeandthebottomdross.Duetothespecificgravityoffloatingdrossbeingl
4、essthanthespecificgravityofzincliquid,thefloatingdrosswillmovetothesurfaceofthezincbath.Duringthismovement,aturbulentflowinducedbythepotrollsenablesthefloatingdrossadheretothestripsurface.Thisresultsinasurfacedefectunacceptableforhighqualitysteelsheets.Thereare2stepsintheformationoffloatingdr
5、ossaftertheGAtoGIbathchemistrychanges.ThefirststepistheprecipitationofFe2Al5duetotheAlandFebeingoverthesolubilitylimitandthenthesecondstepisthetransformationofthebottomdrosstothefloatingdross.Topreventtheformationofthefloatingdrosswetakethefollowingactions:(1)makesureFe2Al5doesnotappearsinthe
6、zincsample,(2)useN2bubblingtoacceleratethereductionofbottomdross,(3)controltheconcentrationoffreeFeandfreeAlandthetemperature,and(4)makesuretheproperdistributionofFe,Al,andFe2Al5duringthetransitionfrommanufacturingGAtomanufacturingGI.壹、前 言連續(xù)熱浸鍍鋅線鋅槽內(nèi)之主要成份為,鋅(99.5%以上)、鋁(0.1-0.3%)及鐵(0.03-0.005%)
7、,生產(chǎn)時(shí)之溫度約460-470℃。中鋼二條連續(xù)熱浸鍍鋅線之產(chǎn)品組合有,純鋅鋼捲(Galvanizedsteelcoil)及鋅鐵合金鋼捲(Galvannealedsteelcoil)二大類。因?yàn)槭褂脝我讳\槽生產(chǎn)二種產(chǎn)品,在製程轉(zhuǎn)換及成份的調(diào)整過(guò)程中,由於自由鋁與自由鐵的反應(yīng)及底渣(Bottomdross,FeZn7,)還原的過(guò)程中,產(chǎn)生大量的浮渣(Floatingdross,Fe2Al5,)。浮渣是鋁與鐵之金屬化合物(Intermetalliccompound),為黑色顆粒狀,直徑