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1、塑料工業(yè)第43卷第3期·102·CHINAPLASTICSINDUSTRY2015年3月超疏水rio2/含氫硅油復合涂層制備及其金屬防腐性能研究術(shù)莫春燕,鄭燕升',王發(fā)龍,胡傳波,莫倩。(1.廣西科技大學生物與化學工程學院,廣西柳州545006;2.廣西科技大學鹿山學院,廣西柳州545616)摘要:采用溶膠凝膠法,以納米rio:和含氫硅油(PMHS)為原料,通過硬脂酸對納米rio:表面進行改性,然后將改性后rio:與含氫硅油復合,經(jīng)機械共混、浸漬提拉、熱處理等過程,形成超疏水復合涂層。涂層表面形貌和疏水
2、性采用傅里葉紅外光譜儀、掃描電鏡、熱重分析儀、接觸角分析儀等進行表征,結(jié)果表明,復合涂層表面具有微/納米雙重粗糙結(jié)構(gòu),與水的靜態(tài)接觸角為155。,滾動角為8。;采用極化曲線和交流阻抗等電化學法對涂層防腐性能進行表征,復合涂層的腐蝕電位相比裸鋼片正移了約0.5V,其腐蝕電流密度從裸鋼片的9.15×10。A/cm下降至8.98×10A/cm,減小了2個數(shù)量級,而相比純PMHS的2.67x10~A/cm2,減小了1個數(shù)量級,顯示了較好的防腐蝕性能。關(guān)鍵詞:含氫硅油;微/納米粗糙結(jié)構(gòu);超疏水;防腐DOI:10.
3、3969/j.issn.1005—5770.2015.03.016中圖分類號:TQ324.21文獻標識碼:A文章編號:1005—5770(2015)03—0102—05PreparationandAntisepticPropertiesofSuper-hydrophobicandAnticorrosiverio2/PMHSCompositeCoatingMOChun-yan。,ZHENGYan-sheng,,WANGFa—long,HUChuan—bo,MOQian(1.SchoolofBiologic
4、alandChemicalEngineering,GuangxiUniversityofScienceandTechnology,Liuzhou545006,China;2.LuShanCollegeofGuangxiUniversityofScienceandTechnology,Liuzhou545616,China)Abstract:Superhydrophobiccoatingswithpolymethylhydrosiloxane(PMHS)andnano—rio2particlesasraw
5、materialswerepreparedbysol—gelmethod.First,thenano·TiO2particlesweremodifiedbystearicacid.Thenthesuperhydrophobicandanti—corrosivecoatingswereformedwithPMHSandmodifiedrio2aftermechancialmixing,dip—coatingandheattreating.Thesurfacestructureandhydrophobici
6、tyofthecompositecoatingwerecharacterizedbyinfraredspectroscopy,scanningelectronmicroscopy,thermogravimetricanalyzerandcontactangleanalyzer.Theresultsindicatedthatthecompositecoatingwithmicro/nanodoubleroughstructurehadastaticcontactangleof155。andarolling
7、angleof8。againstwater.Thecorosionofthecompositecoatingwasrepresentedbyelectrochemicalmethodssuchaspolarizationcurvemeasurementandalternatingcurrentimpedanceapectroscopy.Theresultsshowedtherio2/PMHScompositecoatinghadagoodanti-corosionperformance:compared
8、withthebaresteelsubstrate,itscorosionpotentialhadapositiveshiftforabout0.5Vanditsc0H-0sionelectriccunentdecreasedfr0m9.15×10—4AVcmto898×10-6AVcm..whichreducedbyovertwoordersofmagnitude;comparedwiththepurePMHScoating,itscor