綜述---甲基丙烯酸縮水甘油酯合成及其催化劑研究現(xiàn)狀(review of synthesis of glycidyl methacrylate and its catalysts)

綜述---甲基丙烯酸縮水甘油酯合成及其催化劑研究現(xiàn)狀(review of synthesis of glycidyl methacrylate and its catalysts)

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1、綜述---甲基丙烯酸縮水甘油酯合成及其催化劑研究現(xiàn)狀(Reviewofsynthesisofglycidylmethacrylateanditscatalysts)No.Volume351JiangsuChemicalIndustryVol.35No.12007yearsFebruaryJiangsuChemicalIndustryFeb.2007TechnologicalprogressSynthesisanditsapplicationofglycidylmethacrylateResearchstatusofcatalystsCaiHongCaoZhuXinbao(Schoolofc

2、hemicalengineering,NanjingForestryUniversityJiangsu,Nanjing210037)abstractGlycidylmethacrylate(GMA)isanimportantolefinicmonomerwithepoxygroupSeveralkindsofglycidylmethacrylateareintroducedProcessrouteKeywords:glycidylmethacrylate;methacrylicacid;epoxychloropropane;synthesisCLCnumber:TQ225.24+Thead

3、vantagesanddisadvantagesofvariousprocessroutesarealsoreviewedThefeasibilityofthetwostepmethodisdiscussed,andvariouskindsofringopeningcatalystsandtheiradvantagesarediscussedThedefectsaredescribedindetail.1documentidentificationcode:Aarticlenumber:1002-1116(2007)01-0011-043Glycidylmethacrylate(short

4、forshort)GMA)isamolecularinclusionReactivebifunctionalmonomerswithcarboncarbondoublebondsandepoxygroupsReactionVeryhighactivityItiswidelyusedinthesynthesisandmodificationofpolymermaterials.Thestructureisasfollows:ThesynthesismethodsofGMAhavemanyforeignpatentsButnowThereisalackofcomprehensiveresear

5、chreportsinthisfieldMostofthemareconcentratedinonestepOnthestudyoflaw.ArticleonTheeffectivesynthesismethodofGMAisdiscussed.Synthesisof1GMABeyondseasGMAhasachievedindustrialproductionMethacrylicacidAcidormethylmethacrylate,sodiumhydroxide,epoxychloropropane,etc.rawmaterialSynthesizedbyonesteportwos

6、teps.1.1stepmethodPhasetransfermethod)RawmaterialsareeasytoobtaininonestepMildreactionItiswidelyusedintheworldMethodofuse.First,methacrylicacidandsodiumhydroxideareusedinorganicsolventsMethacrylicacidsodiumsaltwaspreparedbyneutralizationreactionAfterdrying,andPropylenechlorideanditsphasetransferca

7、talystweredehydratedatacertainproportionHightemperatureLowerreactionProductsareobtainedbyvacuumdistillationandwaterwashing.Athomeandabroad,mostoftheresearchandproductioninthisareatakeonestepSynthesismethodTheone-

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